Could you wash these and reuse them since they are plastic coated silicone?

Yup. Do it all the time. There is a soft nubby sheath over the hard white plastic center. Until that wears out (you'll know), keep using it. They last longer if you have perfect teeth. If you have a lot of crowns, to catch at the nubby sheath & tear it, they wear out faster.

How many are in pack?

There are 36 in the pack and a hard plastic case

Are these recyclable or can they only be disposed in the rubbish?

The instructions I have for recycling in my area definitely don't allow silicone. They also don't allow anything that small in the bin, the sorting machines don't work with little things like that.

How many picks are there in one plastic case? The picture only shows 6 pieces. If there are 36 pieces, are there 6 plastic cases?

There is 1 travel case include in each blister pack of 36 pieces.

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